Synergistic combinations of alkane sulfonates and alkoxy hydroxy propane sulfonates



FOAM vownss IN ms.

Aug p16, 1966 w M. BRIGHT 3,267,040 SYNERGISTIC COMBINATIONS 0F ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2. 1960 20 Sheets-Sheet l CYLINDER FOAM VOLUMESDF SODIUM DECANESULFDNATE (SULFATE BUILT} AND LHES (SULEATE BUILT SINCZY AND IN COMB/NATION WITH EACH OTHER 30 SECONDS AFTER FOAM FORMAT ION SQDIUM DECA NE SULFONATE ({U ACTIVE FIG IA INVENTOR.

WILLARD M. BRIGHT his AT T ORNE Y5 Aug. 16, 1966 w. M. BRIGHT 3,267,040

- SYNERGISTIC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2. 1960 20 Sheets-Sheet 2 CYLINDER FOAM VOLUMES OF SOD/UM OEOANESULFONATE (SULFATE BUILT AND LHES (SULFATE BUILT S/NGLY AND IN COMB/NATION WITH EACH OTHER 15 MINUTES AF TER FOAM FORMAT/ON FOAM VOLUMES IN MLSZ 392W...PQMEEQEEQNB l5 l2 9 s 5 o a s 9 l2 l5 7 l8 x ACTIVE F/GZ IB INVENTOR. WILLARD M. BRIGHT FOAM vow/v5.9 //v MLS.

Aug. 16, 1966 w. M. BRIGHT 3,267,040.

' SYNERGISTIC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2. 1960 20 Sheets-Sheet 3 CYLINDER FOAM VOLUMES 0F SOD/UM DODE'CANESULFONATE/SULFATEBUILT} AND THES (SULFATE BUILT}, SING/J AND IN COMB/NATION WITH EACH OTHER '30 55004109 AFTER FOAM FORMAT/0N j. .Q JL 9LQZL $EL S w ESULFQ iZ'i-AI TnEs\aL+, //X/ A IO 7.5 5 B O 2.5 5

x ACTIVE FIG 2A INVENTOR. WILLARD M. BRIGHT hi8 ATTORNEYS FOAM vowuss //v m3.

Aug. 16, 1966 SYNERGISTIC COMBINATIONS OF- ALKANE SULFONATES Original Filed Aug. 2. 1960 w. M. BRIGHT 3,267,040

AND ALKOXY HYDROXY PROPANE SULFONATES 2O Sheets-Sheet 4 CYLINDER FOAM VOLUMES 0F SOD/UM DODECANESULFONATE SULFATE BUILT} AND THES (SULFATE BU /LT), SINGL) AND IN COMB/NAT ION W/TH- EACH 07' HER I5 MINUTES AF TE FOAM FORMAT ION e Tii-fi "W- T '(B) somu m oooscawesuwoyms (A) 2.5 5 I 15 IO ACTIVE mmvron.

WILLARD M. BRIGHT his Mia/avers Aug. 16, 1966 w. M. BRIGHT 3,267,040

SYNERGISTIC COMBINATIONS OF ALKANE SULFONA'IES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2, 196C 20 Sheets-Sheet 5 CYLINDER FOAM vowuss 0F soo/uu DODECANESULFOIVATEIPHOSPHATE BUILT} 'AND mes (PHOSPHATE BU/L r), swa AND nv COMB/NATION w/m 54c 0mm so szcouos AFTER ram ZFORMATION' ACTUAL (A+B) I-OAM VOLUMES M! "Li A l8 l5 l2 9 6 3 0 B 0 3 s 9 l2 l5 I8 94 Acm E mmvrox.

WILLARD M. BRIGHT Aug. 16, 1966 w. M. BRIGHT 3,267,040

' SYNERGISTIC COMBINATIONS 0F ALKANE SULFONATES AND ALKQXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2, 1960 20 Sheets-Sheet 6 CYLINDER FOAM VOLUMES 0F SOD/UM DODECA/VESULFO/VATE (PHOSPHATE BUILT) AND THESIPHOSPHATE BUILT}, .S'INGLY AND IN COMB/NATION WITH EACH OTHER.

[5 MINUTES AFTER FOAM FORMAT/0N expecreoxmm N THES(B) II a "0 SODIUM DODECANEULFONAT E(A) A l8 as :2 9 s a o B o 3 6 9 a2 :5 l8

% ACTIVE INVENTOR. WILLARD M. BRIGHT BY I Q arra'mFrs Aug. 16, 1966 SYNERGISTIC COMBIbiATIONS OF ALKANE SULFONATES Original Filed Aug. 2, 1960 7 w M. BRIGHT 3,267,040

AND ALKOXY HYDROXY PROPANE SULFONATES 20 Sheets-Sheet 7 CYLINDER FOAM VOLUMES 0F SOD/UM DODEGANESULFONATE/NON-BUILT} AND THE? (NON-BUILT}, SINGLY AND //V COMB/NATION WITH EACH OTHER.

30 SECONDS AFTER FOAM FORMAT/0N A100 15 so as o B o as so 15 IOO ACTIVE INVHVTUR.

' WILLARD M. BRIGHT F/G: 44 BY Z 'z/ MM hi; ATTORNEG Aug. 16, 1966 w M. BRIGHT FOAM VOLUMES IN MLS.

SYNERGISTIC COMBIIiATIONS OF' ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2, 1960 20 Sheets-Sheet 8 CYLINDER FOAM KOLUMES OF SOD/UM OOOEOANESULFONATE {NONrBU/LT) AND THE 5 (NON-BUILT}, SINGLY AND IN COMB/NATION WITH EACH OTHER I5 MINUTES AFTER FOAM FORMAT/ON QNATE(A) A o B loo ACTIVE WILLARD $551??? FIG. 45

his AT T ORNE V5 Aug. 16,1966 w M. BRIGHT 3,267,040

SYNERGISTIC COMBIIiATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Flled Aug. 2, 1960 20 Sheets-Sheet 9 CYLINDER FOAM VOLUMES OF SOD/UM DOOEOANESULFONATE (SULFATE BUILT) AND LHES (SULFATE. BUILTI SINOLY AND IN COMBINATION WITH EACH OTHER.

FOAM VOLUMES IN MLS.

30 SECONDS AF TER FOAM FORMAT/ON "SOD/U H 00 v-5 41p I/ m s F AM I00 I r A I8 [5 l2 s s '3 o B 0 3 s 9 l2 :5 w

% .ncrkvs MENTOR WILLARD M. BRIGHT FIG. 5A

his ATTORNEY f BRIGHT 3,267,040

20 Sheets-Sheet 10 V S YNERGISTIC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES 15 MINUTES AFTER FOAM FORMAT/0N Original Filed Aug. 2. 1960 CYLINDER FOAM VOLUMES 0F SOD/UM OODECANESULFO/VATE (SULFATE BUILT AND LHES (SULFATE BUILT); .SINGLY AND //V COMB/NATION WITH EACH OTHER.

INVENTOR. WILLARD M. BRIGHT his ATTORNEYS SODIUM DODECANESULFONATE (A) x ACTIVE FIG 55 BY W Aug. 16, 1966 w. M. BRIGHT 3,257,040

SYNERGISTIC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFQNATES Original Filed Aug. 2, 1960 20 SheetsSheet 11 4-I-e V \k I vi 300 X 5' -kr '3 m ug q Q 2 1 5 x 30 5500/1/05 AFTER FOAM FORMAT/0N lOO v CYLINDER FOAM VOLUMES 0F SOD/UM TE TRADECANESULFONAIE (SULFATE BUILT} AND LHES (SULFATE BUILT}, SINGLY AND IN COMB/NATION WITH 540/1 0mm A l8 l5 l2 9 6 3 '08 L: B 3 6 mmvron 9; 4517115 WILLARD M. BRIGHT W. M. BRIGHT Aug. 16, 1966 SYNERGISTIC COMBINATIONS 0F ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2, 1960 20 Sheets-Sheet l2 CYLINDER FOAM VOLUMES 0F SOD/UM TE TRADECANESULEONATE (SULFATE BUILT) AND LHES (SULFATE BUILT SINGLY AND IN COMB/NATION WITH EACH OTHER /5 MINUTES AFTER FOAM FORMAT/0N m0 AB 6 ACTIVE INVENTOR.

WILLARD M. BRIGHT Aug. 16, 1966 w. M. BRIGHT 3,267,040

SYNERGIS'I'IC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2,1960 v 20 SheetsSheet l3 CYLINDER FOAM VOLUMES OF SODIUM DOOEOANESULFONATE (NON-BUILT) ANO STEPANOI. WAT/ NON-BUILT}, SINGLY AND IN COMBINATION WITH EACH OTHER,

30 SECONDS AF TFI? FOAM FORMATION FOAM VOLUMES IN ML5'.

96 ACTIVE FIG 7A INVENTOR. WILLARD M. BRIGHT fimuf M hi: AT RNEYS W. M. BRIGHT Aug. 16, 1966 r 3,267,040 SYNERGISTIC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES 2O Sheets-Sheet 14 Original Filed Aug. 2. 1960 CYLINDER FOAM VOLUMES 0F SOD/UM DODECAIVE SULFONATE (NON-BUILT) AND STEPA/VOL WAT (NON-BUILT}, .SINGL) AND IN COMB/NAT ION WITH EACH OTHER I5 MINUTES AFTER FOAM FORMAT ION j m E M535 8 F +T L A U L E m TN 0162 C A E r w T HES D M U v m QQ ACTIVE INVENTUR. WILLARD M. BRIGHT By {I his ATTORNEYS I FIG 7B Aug. 16, 1966 w. M. BRIGHT 3,267,040

SYNERGISTIG COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2, 1960 20 Sheets-Sheet l6 CYLINDER FOAM VOLUMES 0F SOD/UM DODECANESULFONATE (SULFATE BUILT) AND STEPANOL WAT (NON-BUILT), SINGLY AND IN COMQWATYO/V WITH EACH OTHER I5 MINUTES AFTER FOAM FORMAT/0N 2 .200 Ac A TUAL H5, 3 \l 9 r EXPECTEBLAW.

A ST EFTTBL WAT(B) a SODIUM DODECANESULFONATE (A) *3 1w 1 A la 5. 2 9 6 3 o a o a 6 9 Q '2 5 m ACTIVE zzvmvron WILLARD M. BRIGHT g- 1966 w. M. BRIGHT 3,267,040

SYNERGISTIC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2, 1960 20 Sheets-Sheet 1? CYLINDER FOAM VOLUMES OF SOD/UM DODECANESULFONATE (NON-BUILD ANO TRITON X-IOO (NON-BUILT), S/NGLY AND IN COMB/NAT ION 57/? H EACH OTHER.

30 SECONDS AFTER FOAM FORMAT/ON INVEN TOR. WILLARD M; BRIGHT his ATTORNEYS Aug. 16, 1966 I w T 3,267,040

SYNERGI STIC COMBINATIONS OF'ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug 2. 1960 '20 Sheets-Sheet 18 .OYLl/VOEI? FOAM VOLUMES OF SODIUM OOOEOANESULFONATE {NON-BUILT} AND T R/T O/V X /OO (NON-BUILT $l/V6LY AND //V COMB/NATION WIT/1' EACH OTHER /5 MINUTES AFTER FOAM FORMATION a, 200 i a ACTUAL(A;l-B)

I F ITON somum DO'JECANESULFQNATE (A) A l8 l5 l2 9 6 3 O B O 3 6 9 l2 l5 l8 9; ACTIVE INVENTOR.

- WILLARD M. BRIGHT 1966 w. M. BRIGHT 3,

. SYNERGISTIC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2. 1960 20 Sheets-Sheet l9 CYLINDER FOAM VOLUMES 0F SOD/UM DODEGA/VESULFONATE (NON-BUILT) A/VD 'ARMEEN (80) (NON-BUILT), SING/J AND IN COMB/NATION WIT/1' EACH OTHER.

30 sEcorvos AFTER r0441 FORMAT/0N aoo ACTUAL (n+9) Q. 6 1 32:11!! Q ,m \9) 1 @SM 8 mo 0 ARMEEN (SDHB) I p A pa 5 l2 8 o a s x AUT/VE IN VEN TOR. WILLARD M. BRIGHT A RNEYS g- 1966 w. M. BRIGHT 3,267,040

SYNERGISTIC COMBINATIONS OF ALKANE SULFONATES AND ALKOXY HYDROXY PROPANE SULFONATES Original Filed Aug. 2. 1960 20 Sheets-Sheet 2O CYLINDER FOAM VOLUME 5 OF SOD/UM DODECANESULFONAT E (NON-BUILT I AND ARMEEN (ED/(NON-BU/LT}, SINGLY AND IN COMB/NATION WITH EACH OTHER 15 MINUTES AFTER FOAM FORMAT/0N SODIUM DODECANESULFONATE (A) u; 200 4 ----ARMEEN (80) (B) 4 m 1 g 3 1::::q::1=1z;= E

REC TED (A+B) A. l8 l5 l2 5 o B 0 s 6 l5 la ACTIVE INVENTOR.

' WILLARD M. BRIGHT 

1. A SYNERGISTIC FOAMING COMPOSITION COMPRISING FROM ABOUT 7.0 TO ABOUT 17.0 PARTS SODIUM DECANE SULFONATE AND FROM ABOUT 11.0 TO ABOUT 1.0 PARTS SODIUM-3-DODECYLOXY-2-HYDROXY PROPANE SULFONATE, RESPECTIVELY; SAID SAID COMPOSITION HAVING AN ACTUAL FOAM VOLUME AFTER 15 MINUTES AGING MORE THA 35 ML. ABOUT THE EXPECTED FOAM VOLUME AND HAVING A MAXIMUM ACTUAL SYNERGISTIC FOAM VOLUME OF AT LEAST ABOUT 190 ML. 